Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
نویسنده
چکیده
In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol-ecules are stacked in columns along the c axis and display inter-molecular π-π inter-actions between the six-membered rings, the shortest centroid-centroid distance being 3.553 (3)Å. Inter-molecular C-H⋯Cl contacts are also noted.
منابع مشابه
A monoclinic polymorph of dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3 N 2,N 1,N 6)manganese(II)
The Mn(II) ion in the title complex, [MnCl(2)(C(18)H(12)N(6))], is five-coordinated in a distorted square-pyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two chloride anions. In the crystal, the pyridyl rings are located approximately parallel to their carrier triazine ring, making dihedral angles of 5.0 (1), 3.8 (1) and 3.2 (1)°. Intramolecul...
متن کاملDibromido(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3 N 2,N 1,N 6)manganese(II)
The Mn(II) ion in the title complex, [MnBr(2)(C(18)H(12)N(6))], is five-coordinated in a distorted square-pyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine (tptz) ligand and two bromide anions. In the crystal, the pyridyl rings coordinated to the Mn atom are inclined slightly to their carrier triazine ring [dihedral angles = 8.0 (3) and 7.5 (3)°], whereas ...
متن کاملDiacetato-κO;κ2 O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3 N 2,N 1,N 6)manganese(II) monohydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol-ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial ...
متن کاملPoly[[(μ3-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu-N 1.962 (3)-2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric network with voids propagated along the b axis. These voids are filled with NO(3) (-) anions with a s...
متن کاملDiaqua(trifluoroacetato-κ2 O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3 N 2,N 1,N 6]manganese(II) trifluoroacetate
The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N',N''-chelated by the neutral N-heterocycle and O,O'-chelated by the carboxyl-ate ion, the five atoms involved in chelation comprising a penta-gon around it. The apical sites of the trans-penta-gonal bipyramidal coordination geometry are occupied by two water mol-e...
متن کامل